461555
(R)-(+)-N-(1-Phenylethyl)maleimide
97%
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About This Item
Empirical Formula (Hill Notation):
C12H11NO2
CAS Number:
Molecular Weight:
201.22
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
optical activity
[α]24/D +61°, c = 2 in ethanol
refractive index
n20/D 1.556 (lit.)
bp
110-115 °C/0.004 mmHg (lit.)
density
1.138 g/mL at 25 °C (lit.)
functional group
imide
maleimide
phenyl
SMILES string
C[C@@H](N1C(=O)C=CC1=O)c2ccccc2
InChI
1S/C12H11NO2/c1-9(10-5-3-2-4-6-10)13-11(14)7-8-12(13)15/h2-9H,1H3/t9-/m1/s1
InChI key
PWZXUQWQRVKGAH-SECBINFHSA-N
Application
This optically active maleimide undergoes radical copolymerization with styrene to yield a ~1:1 copolymer (~98%). Vinyl copolymers with asymmetric main chains can be used as nonlinear optical materials. Dienophile for diastereoselective Diels-Alder reactions.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
235.4 °F - closed cup
Flash Point(C)
113 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Oishi, T. et al.
Polymer, 34, 2644-2644 (1993)
Donnelly, I.H. et al.
J. Chem. Soc. Perkin Trans. II, 1821-1821 (1996)
Baldwin, S.W. et al.
Tetrahedron Letters, 32, 5877-5877 (1991)
Chromatograms
application for HPLC
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