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Merck
CN

463000

Germanium(IV) fluoride

electronic grade, ≥99.9%

Synonym(s):

Germanium tetrafluoride

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About This Item

Linear Formula:
GeF4
CAS Number:
Molecular Weight:
148.63
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
232-011-3
MDL number:
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InChI key

PPMWWXLUCOODDK-UHFFFAOYSA-N

InChI

1S/F4Ge/c1-5(2,3)4

SMILES string

F[Ge](F)(F)F

grade

electronic grade

assay

≥99.9%

form

liquid

reaction suitability

core: germanium

mp

−36.5 °C (lit.)

transition temp

sublimation point -36.5 °C

density

2.46 g/mL at -37 °C (lit.)

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General description

Atomic number of base material: 32 Germanium

Application

Germanium(IV) fluoride in combination with disilane gas has recently been used to fabricate SiGe crystallites directly on glass substrates. Intense visible light emission from Ge and Si nanocrystals is of particular interest because of potential uses in optoelectronic devices.
Employed in studies on room-temperature oxidation of noble metals and the fabrication of SiGe crystallites on glass substrates.

Packaging

Packaged in electropolished stainless steel lecture bottle with a stainless steel valve and CGA 330 outlet.

Other Notes

Monel gas regulators Z562483 or Z405981 (CGA 330) are recommended.
Requires 316 SS gas regulator Z173959 or Z173967.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

2A - Gases

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Journal of Non-Crystalline Solids, 198-200, 879-879 (1996)
Eur. J. Solid State Inorg. Chem., 33, 809-809 (1996)

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