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464309

Methoxyperfluorobutane

Name: Methoxyperfluorobutane
Brand: ALDRICH

99%, mixture of n- and iso-butyl isomers

Synonym(s):

Nonafluorobutyl methyl ether, HFE-7100, Methoxynonafluorobutane, Methoxyperfluorobutane, Nonafluoromethoxybutane

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About This Item

Linear Formula:

CH₃OCF₂R, R = -CF₂CF₂CF₃ or -CF(CF₃)₂

CAS Number:

163702-07-6

Molecular Weight:

250.06

MDL number:

MFCD28505595

UNSPSC Code:

12352100

PubChem Substance ID:

24870162

NACRES:

NA.22

Beilstein/REAXYS Number:

8768491

Assay:

99%

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Properties

Quality Level

100

assay

99%

refractive index

n20/D 1.3 (lit.)

bp

60 °C (lit.)

mp

−135 °C (lit.)

density

1.52 g/mL at 25 °C (lit.)

functional group

ether, fluoro

SMILES string

COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F.COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F

InChI

1S/2C5H3F9O/c1-15-5(13,14)3(8,9)2(6,7)4(10,11)12;1-15-5(13,14)2(6,3(7,8)9)4(10,11)12/h2*1H3

InChI key

OKIYQFLILPKULA-UHFFFAOYSA-N

Description

Application

Methoxyperfluorobutane can be used as a solvent:

In the synthesis of various aryl fluoride derivatives via electrophilic fluorination of aryl and heteroaryl Grignard reagents.
In grafting of fluorinated diblock copolymers onto silica particles.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Coating of silica particles by fluorinated diblock copolymers and use of the resultant silica for superamphiphobic surfaces

Grozea CM, et al.

Polymer, 64(12), 153-162 (2015)

Fluorinated colloidal emulsion of photochangeable rheological behavior as a sacrificial agent to fabricate organic, three-dimensional microstructures.

Li-Hsin Han et al.

Langmuir : the ACS journal of surfaces and colloids, 26(9), 6108-6110 (2010-03-31)

Three-dimensional organic microfabrication, an emerging technology, faces the challenge of lacking a sacrificial agent (SA) to temporarily support the formation of microscale geometries, which can be removed after a microstructure is constructed. In this study, an ultradense oil-in-organofluorine colloidal emulsion

Characterization by NMR of reactants and products of hydrofluoroether isomers, CF3(CF2)3OCH3 and (CF3)2C(F)CF2OCH3, reacting with isopropyl alcohol.

Howard C Knachel et al.

Magnetic resonance in chemistry : MRC, 51(7), 407-413 (2013-05-25)

The 3M Company product Novec™ 71IPA DL, a mixture of methoxyperfluorobutane, methoxyperfluoroisobutane and 4.5 wt.% isopropyl alcohol, has been found to be very stable at ambient temperature, producing fluoride at the rate of ~1 ppm/year. Our earlier kinetic and theoretical studies have

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Global Trade Item Number

SKU	GTIN
464309-100ML	04061832356136
464309-500ML	04061837673467