464384
(S)-(−)-2-Hydroxy-4-(2-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaphosphorinane 2-oxide
97%
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About This Item
Empirical Formula (Hill Notation):
C12H17O5P
CAS Number:
Molecular Weight:
272.23
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
97%
optical activity
[α]22/D −59°, c = 1 in methanol
mp
194-196 °C (lit.)
functional group
phosphate
storage temp.
2-8°C
SMILES string
COc1ccccc1[C@H]2OP(O)(=O)OCC2(C)C
InChI
1S/C12H17O5P/c1-12(2)8-16-18(13,14)17-11(12)9-6-4-5-7-10(9)15-3/h4-7,11H,8H2,1-3H3,(H,13,14)/t11-/m1/s1
InChI key
HNFXKRNIAWHFJN-LLVKDONJSA-N
Related Categories
Application
Chiral phosphoric acid used for the resolution of amines, amino acids, and amino alcohols.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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ten Hoeve, W. and Wynberg, H.
Synthetic Communications, 24, 899-899 (1994)
A.D. van der Maest et al.
Rec. Trav. Chim., 109, 523-523 (1990)
ten Hoeve, W., and Wynberg, H.
The Journal of Organic Chemistry, 50, 4508-4508 (1985)
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