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Merck
CN

464600

Zirconium(IV) acetate hydroxide

Synonym(s):

Dihydroxy-bis(methoxycarbonyloxy)zirconium, Hydroxy-tris(methoxycarbonyloxy)zirconium

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About This Item

Linear Formula:
(CH3CO2)xZr(OH)y, x+y ~4
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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InChI

1S/6C2H4O3.6H2O.3Zr/c6*1-5-2(3)4;;;;;;;;;/h6*1H3,(H,3,4);6*1H2;;;/q;;;;;;;;;;;;3*+4/p-12

InChI key

RAVMIOKPFXMREI-UHFFFAOYSA-B

SMILES string

COC(=O)O[Zr](O)(O)O.COC(=O)O[Zr](O)(O)OC(=O)OC.COC(=O)O[Zr](O)(OC(=O)OC)OC(=O)OC

form

powder

composition

Zr, 40.4-43.3% gravimetric

reaction suitability

core: zirconium

Quality Level

Application

Zirconium(IV) acetate hydroxide can be used as a precursor to synthesize:
  • Monoclinic zirconium dioxide nanoparticles via thermal treatment method in the presence of polyvinylpyrrolidone as a capping agent.
  • Zirconia doped lithium cobalt oxide (Zr-LiCoO2) by treating with lithium acetate and cobalt acetate via the sol-gel method.
  • Yttrium stabilized zirconia nanoparticles via co-precipitation method using yttrium acetate tetrahydrate and oxalic acid dehydrate.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Structural and optical properties of zirconia nanoparticles by thermal treatment synthesis
Keiteb Aysar S, et al.
Journal of Nanomaterials, 2016 (2016)
Synthesis and characterization of yttrium stabilized zirconia nanoparticles
Maridurai T, et al.
Materials Research, 19, 812-816 (2016)
Electrochemical properties of LiMxCo1- xO2 [M= Mg, Zr] prepared by sol-gel process
Kim Hyung-Sun, et al.
Journal of Power Sources, 138(1-2), 232-239 (2004)

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