464635
Trifluoromethanesulfonimide
≥95.0% (19F-NMR)
Synonym(s):
Bis(trifluoromethanesulfonyl)amine
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About This Item
Linear Formula:
(CF3SO2)2NH
Molecular Weight:
281.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4754101
Assay:
≥95.0% (19F-NMR)
Form:
solid
Quality Level
assay
≥95.0% (19F-NMR)
form
solid
bp
90-91 °C (lit.)
mp
46-57 °C (lit.)
functional group
fluoro
SMILES string
FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F
InChI
1S/C2HF6NO4S2/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h9H
InChI key
ZXMGHDIOOHOAAE-UHFFFAOYSA-N
General description
Trifluoromethanesulfonimide is a promising Bronsted acid catalyst and is superior to scandium triflate in catalytic action.
Application
Trifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Trifluoromethanesulfonimide catalysed synthesis of 1-substituted-1H-1, 2, 3, 4-tetrazoles using glycerol as green solvent at room temperature.
Wang H, et al.
J. Chem. Res. (M), 40(9), 570-572 (2016)
Practical Synthesis of (?)-a-Tocopherol. Trifluoromethanesulfonimide as an Extremely Active Br?nsted Acid Catalyst for the Condensation of Trimethylhydroquinone with Isophytol.
Ishihara K, et al.
Synlett, 11, 1045-1046 (1996)
Youngbum Kim et al.
Nanoscale, 10(18), 8851-8858 (2018-05-02)
The exciton-dominated light emission of two-dimensional (2D) semiconductors is determined largely by the doping state and the formation of defects. Extensive studies have shown that chemical treatment critically modifies the doping state and defect state of chemical vapor deposition (CVD)-grown
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 464635-5G | 04061832356600 |