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464872

Lithium diphenylphosphide solution

0.5 M in THF

Synonym(s):

Diphenyl lithium phosphide, Diphenylphosphine lithium salt, Diphenylphosphino)lithium, Lithiodiphenyl phosphide, Lithiodiphenylphosphine

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About This Item

Linear Formula:
(C6H5)2PLi
CAS Number:
65567-06-8
Molecular Weight:
192.12
NACRES:
NA.22
PubChem Substance ID:
24870228
UNSPSC Code:
12352002
MDL number:
MFCD00046054
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Quality Segment

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

concentration

0.5 M in THF

bp

65-67 °C

density

0.925 g/mL at 25 °C

SMILES string

[Li]P(c1ccccc1)c2ccccc2

InChI

1S/C12H10P.Li/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChI key

WKUYEGHEUWHKIU-UHFFFAOYSA-N

Signal Word

Danger

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

Flash Point (°F)

-4.0 °F - closed cup

Flash Point (°C)

-20 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

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