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Merck
CN

469610

Poly[4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole-co-tetrafluoroethylene]

dioxole 65 mol %

Synonym(s):

PTFE AF, PTFE AF 1600

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About This Item

CAS Number:
UNSPSC Code:
12352103
NACRES:
NA.23
MDL number:
Technical Service
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Quality Level

description

contact angle 104 ° with water, critical surface energy 15.7 dyn/cm

form

solid

composition

dioxole, 65 mol %

dielectric constant

1.934, 1 MHz (ASTM D 150)

hardness

103 (Rockwell, ASTM D 785, 23 °C)

transmittance

>95% (ASTM D 1003)

refractive index

n20/D 1.31

density

1.78 g/mL at 25 °C

SMILES string

FC(F)(F)C1(OC(=C(O1)F)F)C(F)(F)F.FC(=C(F)F)F

InChI key

WAQVMMYKXQPUNG-UHFFFAOYSA-N

General description

Poly[4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole-co-tetrafluoroethylene] (AF1600) is a fluorinated polymer that is formed by the copolymerization of 2,2-bis(trifluoromethyl)- 4,5-difluoro-1,3-dioxole and 1,1,2,2,- tetrafluoroethylene. It is an optically transparent photo-stable polymer with a high glass transition temperature (Tg), which can be used as a coating in electrochemical and electronic devices.
A tunable, polymeric, photonic material.

Application

AF1600 can form a hydrophobic coating on a silicon wafer that has a contact angle in the range of 115-120° which can be potentially used in agrochemical and printing applications. It may also form a self-assembled monolayer (SAM) on aluminum plates which can be used in the fabrication of water driven triboelectric nanogenerators (WTENGs).
Optically transparent due to the cycloether moieties in the structure which prevent crystallization. Also possesses nonadhesive characteristics and low refractive index making it more interesting than PTFE for optical applications.
Optoelectronic devices for optical clarity, low-refractive index coating for optical devices, protective coating for chemical resistance, release coating, and sight window for harsh chemical environments.
Used as a fluoropolymer for 157-nm lithography.

Physical form

Amorphous copolymer.


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Theoretical study of micro/nano roughness effect on water-solid triboelectrification with experimental approach
Lee J and Hwang W
Nano Energy, 52(1), 315-322 (2018)
Preparation of Superhydrophobic Teflon AF 1600 Sub-Micron Fibers and Yarns Using the Forcespinning? Technique.
Rane Y, et al.
Journal of Engineered Fibers and Fabrics, 8(4) (2013)
Wetting of hydrophobic substrates by pure surfactants at continuously increasing humidity
Ivanova NA, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 519(1), 71-77 (2017)



Global Trade Item Number

SKUGTIN
469610-1G04061832359045