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470775

Vanadium(V) oxytriethoxide

Name: Vanadium(V) oxytriethoxide
Brand: ALDRICH

95%

Synonym(s):

Ethyl orthovanadate, Oxovanadium triethoxide, Tri(ethoxy)vanadium oxide, Triethoxyvanadyl, Triethyl vanadate, Vanadium oxytriethoxide

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About This Item

Linear Formula:

OV(OC₂H₅)₃

CAS Number:

1686-22-2

Molecular Weight:

202.12

NACRES:

NA.23

PubChem Substance ID:

24870679

UNSPSC Code:

12352103

EC Number:

216-870-1

MDL number:

MFCD00799170

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Properties

Quality Level

100

assay

95%

reaction suitability

core: vanadium, reagent type: catalyst

bp

125-128 °C (lit.)

density

1.139 g/mL at 25 °C (lit.)

SMILES string

CCO[V](=O)(OCC)OCC

InChI

1S/3C2H5O.O.V/c3*1-2-3;;/h3*2H2,1H3;;/q3*-1;;+3

InChI key

IOHMVQGDVUCILM-UHFFFAOYSA-N

Description

Application

Building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Stepwise Cluster Assembly Using VO(2)(acac) as a Precursor: cis-[VO(OCH(CH(3))(2))(acac)(2)], [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)], [V(3)O(3){&mgr;,&mgr;-(OCH(2))(3)CCH(3)}(2)(acac)(2)(OC(2)H(5))], and [V(4)O(4)(&mgr;-O)(2)(&mgr;-OCH(3))(2)(&mgr;(3)-OCH(3))(2)(acac)(2)(OCH(3))(2)].2CH(3)CN(1).

Feilong Jiang et al.

Inorganic chemistry, 37(21), 5439-5451 (2001-10-24)

The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alcohol-containing solvents. The neutral mono-, di-, tri-, and tetranuclear oxovanadium(V) complexes [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)] (1)

Global Trade Item Number

SKU	GTIN
470775-25ML	04061838147363
470775-5ML	04061838140579