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Merck
CN

47676

Formaldehyde dimethyl acetal

absolute, over molecular sieve (H2O ≤0.01%), ≥99.0% (GC)

Synonym(s):

Dimethoxymethane, Methylal

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About This Item

Linear Formula:
CH2(OCH3)2
CAS Number:
Molecular Weight:
76.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-714-2
Beilstein/REAXYS Number:
1697025
MDL number:
Assay:
≥99.0% (GC)
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grade

absolute

Quality Segment

assay

≥99.0% (GC)

quality

over molecular sieve (H2O ≤0.01%)

refractive index

n20/D 1.354

density

0.860 g/mL at 20 °C (lit.)

functional group

acetal, ether

SMILES string

COCOC

InChI

1S/C3H8O2/c1-4-3-5-2/h3H2,1-2H3

InChI key

NKDDWNXOKDWJAK-UHFFFAOYSA-N

General description

Formaldehyde dimethyl acetal (FDA, FDMA, FADMA, dimethoxymethane, DMM, methylal) is a biodegradable dimethyl acetal. It has been synthesized by condensing formaldehyde with methanol in the presence of acid catalyst. It is amphiphilic in nature with low viscosity, surface tension and boiling point. It is a flammable, highly volatile solvent with excellent dissolving power. It is reported to form trimethylorthoformate by anodic methoxylation in basic methanol.

Application

Formaldehyde dimethyl acetal may be used in the following studies:
  • Synthesis of methoxymethyl (MOM) ethers.
  • As an external cross-linker to form microporous polymers.
  • Dehydration of biological samples for scanning electron microscopy (SEM).


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Pictograms

Flame

Signal Word

Danger

Hazard Codes

Hazard Classifications

Flam. Liq. 2

supp_hazards

Storage Class

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

-0.4 °F - closed cup

Flash Point (°C)

-18 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves



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