494070
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine
90%
Synonym(s):
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine
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About This Item
Empirical Formula (Hill Notation):
C15H9Br2N3
CAS Number:
Molecular Weight:
391.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
90%
Product Name
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine, 90%
InChI
1S/C15H9Br2N3/c16-14-8-2-6-12(19-14)10-4-1-5-11(18-10)13-7-3-9-15(17)20-13/h1-9H
SMILES string
Brc1cccc(n1)-c2cccc(n2)-c3cccc(Br)n3
InChI key
PYMBATDYUCQLBC-UHFFFAOYSA-N
assay
90%
mp
257-263 °C (lit.)
functional group
bromo
Quality Level
Application
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine may be used in the synthesis of a novel disubstituted terpyridine ligand.
General description
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine is a substituted terpyridine that can be synthesized from 2,6-dibromopyridine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Kogularamanan Suntharalingam et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(47), 15133-15141 (2012-10-13)
A new disubstituted terpyridine ligand and the corresponding tri-copper(II) complex have been prepared and characterised. The binding affinity and binding mode of this tri-copper complex (as well as the previously reported mono- and di-copper analogues) towards duplex DNA were determined
A Novel One-Pot Synthesis of 6,6''-Dibromo-2,2':6'2''-terpyridine.
Uchida Y, et al.
ChemInform, 26(50) (1995)
Lingjing Chen et al.
Dalton transactions (Cambridge, England : 2003), 48(26), 9596-9602 (2019-02-20)
A new pentadentate quinoline-pyridine ligand and its iron (1), cobalt (2) and nickel (3) complexes have been synthesized and characterized. The iron complex exhibits excellent photocatalytic activity towards CO2-to-CO conversion with a TON(CO) of 544 and a selectivity of 99.3%
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