497746
Butylzinc bromide solution
0.5 M in THF
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About This Item
Linear Formula:
CH3(CH2)3ZnBr
CAS Number:
Molecular Weight:
202.41
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Product Name
Butylzinc bromide solution, 0.5 M in THF
InChI
1S/C4H9.BrH.Zn/c1-3-4-2;;/h1,3-4H2,2H3;1H;/q;;+1/p-1
SMILES string
CCCC[Zn]Br
InChI key
HMBGXQKLGHIDMN-UHFFFAOYSA-M
concentration
0.5 M in THF
density
0.958 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Related Categories
Application
Butylzinc bromide is an organozinc compound, which can be used as a reagent:
- In palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bond by reacting with organic halides or triflates.
- To prepare n-butylanisole by treating with 4-bromoanisole in the presence of a tetraphosphine ligand and a palladium catalyst.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
wgk
WGK 3
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Regulatory Information
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Synthesis of all-cis-3-(2-diphenylphosphinoethyl)-1, 2, 4-tris (diphenylphosphinomethyl) cyclopentane (Ditricyp) from dicyclopentadiene
Kondolff I, et al.
Tetrahedron, 63(38), 9514-9521 (2007)
Room-temperature Negishi cross-coupling of unactivated alkyl bromides with alkyl organozinc reagents utilizing a Pd/N-heterocyclic carbene catalyst
Hadei N, et al.
The Journal of Organic Chemistry, 70(21), 8503-8507 (2005)
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