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499307

苯乙基溴化锌 溶液

0.5 M in THF

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关于此项目

线性分子式:
C6H5CH2CH2ZnBr
化学文摘社编号:
308796-14-7
分子量:
250.45
NACRES:
NA.22
PubChem Substance ID:
24873270
UNSPSC Code:
12352103
MDL number:
MFCD01311437
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Quality Segment

100

concentration

0.5 M in THF

bp

65 °C

density

0.965 g/mL at 25 °C

functional group

phenyl

storage temp.

2-8°C

SMILES string

Br[Zn]CCc1ccccc1

InChI

1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1

InChI key

SEXSOTWHLBYVNF-UHFFFAOYSA-M

Application

Phenethylzinc bromide can be used as a reagent:
  • In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
  • To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
  • To synthesize benzyl substituted thienopyrimidine derivatives.

Legal Information

Rieke ® Metals, Inc. 的产品，®Rieke Metals, Inc. 的注册商标

signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH014,EUH019

存储类别

3 - Flammable liquids

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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