499307
苯乙基溴化锌 溶液
0.5 M in THF
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关于此项目
线性分子式:
C6H5CH2CH2ZnBr
化学文摘社编号:
分子量:
250.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
SMILES string
Br[Zn]CCc1ccccc1
InChI key
SEXSOTWHLBYVNF-UHFFFAOYSA-M
concentration
0.5 M in THF
bp
65 °C
density
0.965 g/mL at 25 °C
functional group
phenyl
storage temp.
2-8°C
Quality Level
Application
Phenethylzinc bromide can be used as a reagent:
- In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
- To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
- To synthesize benzyl substituted thienopyrimidine derivatives.
Legal Information
Rieke ® Metals, Inc. 的产品，®Rieke Metals, Inc. 的注册商标
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
法规信息
新产品
此项目有
Substituted thieno [2, 3-d] pyrimidines as adenosine A2A receptor antagonists
Shook BC, et al.
Bioorganic & Medicinal Chemistry Letters, 23(9), 2688-2691 (2013)
Non-peptidic small molecule inhibitors of XIAP
Park C-M, et al.
Bioorganic & Medicinal Chemistry Letters, 15(3), 771-775 (2005)
Palladium-catalyzed aerobic oxidative cross-coupling reactions of terminal alkynes with alkylzinc reagents
Chen M, et al.
Journal of the American Chemical Society, 132(12), 4101-4103 (2010)
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