510033
Raney®-Nickel
W.R. Grace and Co. Raney® 2400, slurry, in H2O, active catalyst
Synonym(s):
Raney Ni, Nickel sponge
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About This Item
Linear Formula:
AlNi
CAS Number:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
Quality Level
form
slurry
reaction suitability
core: nickel, reagent type: catalyst
manufacturer/tradename
W.R. Grace and Co. Raney® 2400
concentration
in H2O
SMILES string
[Al].[Ni]
InChI
1S/Al.Ni
InChI key
NPXOKRUENSOPAO-UHFFFAOYSA-N
Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
Marilia O S Seijo et al.
Journal of dental education, 77(5), 648-655 (2013-05-10)
Including students' perceptions in the educational process is considered a key component in monitoring the quality of academic programs. This study aimed to evaluate the concept of one's learning experience in endodontic teaching from the perspective of a group of
Fariborz Amini et al.
International journal of orthodontics (Milwaukee, Wis.), 24(1), 43-44 (2013-06-05)
In this report, we present an uncomplicated approach to overcome lingual rolling of mandibular molars during orthodontic treatment, by using rectangular NiTi arch wire in twist fashion through the molar tube. The sequential steps of the twist manoeuvre on a
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 510033-500G | 04061832490045 |
| 510033-100G | 04061832490021 |