510033
Raney®-Nickel
W.R. Grace and Co. Raney® 2400, slurry, in H2O, active catalyst
Synonym(s):
Raney Ni, Nickel sponge
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About This Item
Linear Formula:
AlNi
CAS Number:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
Quality Level
form
slurry
reaction suitability
core: nickel, reagent type: catalyst
manufacturer/tradename
W.R. Grace and Co. Raney® 2400
concentration
in H2O
SMILES string
[Al].[Ni]
InChI
1S/Al.Ni
InChI key
NPXOKRUENSOPAO-UHFFFAOYSA-N
Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Marilia O S Seijo et al.
Journal of dental education, 77(5), 648-655 (2013-05-10)
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A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
Palatally anchored maxillary molar mesialization using the mesialslider.
Benedict Wilmes et al.
Journal of clinical orthodontics : JCO, 47(3), 172-179 (2013-05-11)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 510033-500G | 04061832490045 |
| 510033-100G | 04061832490021 |