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Merck
CN

517909

Luperox® A75, Benzoyl peroxide

75%, remainder water

Synonym(s):

Benzoyl peroxide, Dibenzoyl peroxide

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About This Item

Linear Formula:
(C6H5CO)2O2
CAS Number:
Molecular Weight:
242.23
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
984320
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Quality Level

assay

75%

autoignition temp.

176 °F

reaction suitability

reagent type: oxidant

mp

105 °C (lit.)

storage temp.

2-8°C

SMILES string

O=C(OOC(=O)c1ccccc1)c2ccccc2

InChI

1S/C14H10O4/c15-13(11-7-3-1-4-8-11)17-18-14(16)12-9-5-2-6-10-12/h1-10H

InChI key

OMPJBNCRMGITSC-UHFFFAOYSA-N

General description

Benzoyl peroxide belongs to a family of peroxides. It consists of two benzoyl groups bridged by peroxide link.Benzoyl peroxide has low solubility in water and ethanol.

Application

Benzoyl peroxide can be used as:
  • An oxidizing agent in the synthesis of conducting polypyrrole via inverted emulsion polymerization.
  • An mild oxidizing agent and carboxylate source in the synthesis of substituted imides.
  • A radical initiator in the preparation of PCL/CNF:MX (poly(ε-caprolactone)/cellulose nanofibrils: compatibilizer) bio-nanocomposites.
Widely used initiator, curing agent, and cross-linking agent in polymerization processes.

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.


signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Org. Perox. B - Skin Sens. 1

Storage Class

4.1A - Other explosive hazardous materials

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品

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Development of a sensitive long path absorption photometer to quantify peroxides in aerosol particles (Peroxide-LOPAP)."
Mertes P, et al.
Atmospheric Measurement Techniques, 5(10), 2339-2348 (2012)
Tahani Kaldéus et al.
ACS nano, 13(6), 6409-6420 (2019-05-16)
A molecularly engineered water-borne reactive compatibilizer is designed for tuning of the interface in melt-processed thermoplastic poly(caprolactone) (PCL)-cellulose nanocomposites. The mechanical properties of the nanocomposites are studied by tensile testing and dynamic mechanical analysis. The reactive compatibilizer is a statistical
Tobias Brandhofer et al.
The Journal of organic chemistry, 84(20), 12992-13002 (2019-08-29)
A simple and mild Cu-catalyzed oxidative three-component oxidative Ugi-type method for the synthesis of a variety of substituted imides has been developed. In this direct imidation approach, benzoyl peroxide serves as both the oxidant and the carboxylate source, allowing not



Global Trade Item Number

SKUGTIN
VBP00104-1G04061825181547
517909-100G04061835521395
517909-500G04061835563265
517909-5G04061835563272