521582
1-Chloro-6-iodohexane
96%
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About This Item
Linear Formula:
I(CH2)6Cl
CAS Number:
Molecular Weight:
246.52
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
252-144-0
MDL number:
Assay:
96%
InChI key
QTJHNJCILMMRIQ-UHFFFAOYSA-N
InChI
1S/C6H12ClI/c7-5-3-1-2-4-6-8/h1-6H2
SMILES string
ClCCCCCCI
assay
96%
refractive index
n20/D 1.5230 (lit.)
bp
110 °C (lit.)
density
1.623 g/mL at 25 °C (lit.)
functional group
chloro, iodo
Quality Level
Related Categories
General description
1-Chloro-6-iodohexane is an α,ω-dihaloalkane. 1,12-dichlorododecane is formed as a major product from the reduction of 1-chloro-6-iodohexane with nickel(I) salen. It affords 8-chloro-1-octyne on coupling with sodium acetylide.
Application
1-Chloro-6-iodohexane may be used in the preparation of 1,14-dichloro-7-tetradecyne and 10-2′-(methylphenyl)-7-decynyl chloride.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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New synthesis of meromycolic acid.
Gensler WJ, et al.
The Journal of Organic Chemistry, 44(21), 3643-3652 (1979)
Synthesis of Methyl 11-(2'-Methylphenyl) undecanoate.
Michael WR.
Journal of Chemical and Engineering Data, 11(1), 134-135 (1996)
Homogeneous catalytic reduction of a, ?-dihaloalkanes with electrogenerated nickel (I) salen.
Mubarak MS and Peters DG.
Journal of Electroanalytical Chemistry, 388(1), 195-198 (1995)
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