522996
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
97%
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About This Item
Empirical Formula (Hill Notation):
C5H8N4O
CAS Number:
Molecular Weight:
140.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
216-790-7
MDL number:
Assay:
97%
InChI key
NXFQWRWXEYTOTK-UHFFFAOYSA-N
InChI
1S/C5H8N4O/c1-3-7-4(6)9-5(8-3)10-2/h1-2H3,(H2,6,7,8,9)
SMILES string
COc1nc(C)nc(N)n1
assay
97%
mp
258-261 °C (lit.)
General description
2-Amino-4-methoxy-6-methyl-1,3,5-triazine is formed during the photocatalytic decomposition of sulfonylurea (Sus) herbicide. It is also formed as a thermal decomposition product of chlorsulfuron (a sulfonylurea herbicide) and has been determined by GC using nitrogen-phosphorus detection (NPD).
Application
2-Amino-4-methoxy-6-methyl-1,3,5-triazine may be used in the synthesis of thifensulfuron.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Synthesis of Thifensulfuron Using Bis (trichloromethyl) carbonate.
Yao RS, et al.
Chinese Journal of Applied Chemistry / Ying Yong Hua Xue, 19(7), 687-689 (2002)
Analysis of sulfonylurea herbicides by gas-liquid chromatography. 1. Formation of thermostable derivatives of chlorsulfuron and metsulfuron-methyl.
Klaffenbach P and Holland PT.
Journal of Agricultural and Food Chemistry, 41(3), 388-395 (1993)
Photocatalytic degradation of sulfonylurea herbicides in aqueous TiO 2.
Vulliet E, et al.
Applied Catalysis. B, Environmental, 38(2), 127-137 (2002)
Analysis of sulfonylurea herbicides by gas-liquid chromatography. 2. Determination of chlorsulfuron and metsulfuron-methyl in soil and water samples.
Klaffenbach P and Holland PT.
Journal of Agricultural and Food Chemistry, 41(3), 396-401 (1993)
Rajae Chahboune et al.
Rapid communications in mass spectrometry : RCM, 29(15), 1370-1380 (2015-07-07)
Sulfonylureas are among the most important class of antidiabetic and herbicides. Solar light excitation and Advanced Oxidation Processes may result in the formation of a wide array of products owing to the relative complex structure. These products, that should be
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