525537
2-Amino-5-bromo-3-methylpyridine
97%
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About This Item
Empirical Formula (Hill Notation):
C6H7BrN2
CAS Number:
Molecular Weight:
187.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Product Name
2-Amino-5-bromo-3-methylpyridine, 97%
InChI
1S/C6H7BrN2/c1-4-2-5(7)3-9-6(4)8/h2-3H,1H3,(H2,8,9)
SMILES string
Cc1cc(Br)cnc1N
InChI key
KBLGGRWUEVCNPY-UHFFFAOYSA-N
assay
97%
mp
88-95 °C (lit.)
functional group
bromo
Quality Level
Application
2-Amino-5-bromo-3-methylpyridine may be used to synthesize:
- 5-bromo-2-chloro-3-methylpyridine
- 2-azidopyridine 1-oxide
- 2-amino-5-bromo-3-methylpyridine 1-oxide
- 2,5-dibromo-3-methyl pyridine
- ethyl-3,6-dibromo-8-methylimidazo[1,2-a]pyridine-2-carboxylate
General description
2-Amino-5-bromo-3-methylpyridine can be prepared from 2-amino-3-methylpyridine, via bromination.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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2, 5-and 5, 6-Dihalonicotinic acids and their precursors.
Setliff FL.
Journal of Chemical and Engineering Data, 15(4), 590-591 (1970)
Microwave-Assisted One-Pot Synthesis of Substituted 3-Bromoimidazo [1, 2-a] pyridines and Imidazoheterocycles.
Patil SM, et al.
Journal of Heterocyclic Chemistry, 51(5), 1509-1515 (2014)
Synthesis of the grass alkaloid perlolidine through a pyridyne cyclisation reaction.
Kessar SV and Singh P.
Indian J. Chem. B, 40(11), 1129-1131 (2001)
Ring contraction of 2-azidopyridine 1-oxides and related compounds. 2-Cyano-1-hydroxypyrroles and-imidazoles.
Abramovitch RA and Cue Jr BW.
Journal of the American Chemical Society, 98(6), 1478-1486 (1976)
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