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529621

Bis(triphenylphosphine)nickel(II) dichloride

99.99% trace metals basis

Synonym(s):

NiCl2(PPh3)2, Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride

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About This Item

Linear Formula:
[(C6H5)3P]2NiCl2
CAS Number:
14264-16-5
Molecular Weight:
654.17
NACRES:
NA.23
PubChem Substance ID:
24877695
UNSPSC Code:
12352300
EC Number:
238-154-8
MDL number:
MFCD00009592
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product line

CVD & ALD Precursors

assay

99.99% trace metals basis

form

powder or crystals

reaction suitability

core: nickel

mp

250 °C (dec.) (lit.)

SMILES string

Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

ZBRJXVVKPBZPAN-UHFFFAOYSA-L

Application

Ni(PPh3)2Cl2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine.

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Codes

H317,H350,H412

Hazard Classifications

Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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