532126
Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)
97%
Synonym(s):
Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium
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About This Item
InChI
1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
SMILES string
Cl[Zr]Cl.[CH]1[CH][C](CC[C]2[CH][CH][C]3CCCC[C]23)[C]4CCCC[C]14
InChI key
AKXWJOYQORUUHS-UHFFFAOYSA-L
assay
97%
reaction suitability
core: zirconium, reagent type: catalyst
mp
267-271 °C (lit.)
Quality Level
Related Categories
Application
- Regiochemistry in Negishi carboaluminations
- Polymerization of olefins
- Diastereoselective intramolecular olefin alkylations
- Asymmetric carbomagnesiation
- Reduction of esters to alcohols
- Enantioselective synthesis of allylic amines
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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