532207
2-Chloro-N-methylaniline
97%
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About This Item
Linear Formula:
ClC6H4NHCH3
CAS Number:
Molecular Weight:
141.60
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C7H8ClN/c1-9-7-5-3-2-4-6(7)8/h2-5,9H,1H3
SMILES string
CNc1ccccc1Cl
InChI key
WGNNILPYHCKCFF-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.579 (lit.)
bp
218 °C (lit.)
density
1.15 g/mL at 25 °C (lit.)
General description
2-Chloro-N-methylaniline (2-Cl-N-MA), also known as N-methyl-2-chloroaniline, is a secondary amine. The iridium-catalyzed borylation of 2-Cl-N-MA affords the correponding ortho-borylated derivative.
Application
2-Chloro-N-methylaniline (N-Methyl-2-chloroaniline) may be used in the synthesis of 2-chloro-N-methylaniline-blocked polyisocyanate and N-methyl-N-nitro-2-chloroaniline.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
197.6 °F - closed cup
flash_point_c
92 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Amine?blocked polyisocyanates. I. Synthesis of novel N?methylaniline?blocked polyisocyanates and deblocking studies using hot?stage fourier transform infrared spectroscopy.
Sankar G and Nasar AS.
Journal of Polymer Science Part A: Polymer Chemistry, 45(8), 1557-1570 (2007)
Molecular and crystal structures of N-methyl-N-nitro-2-chloroaniline.
Prezhdo VV, et al.
Crystallography Reports, 46(3), 389-393 (2001)
Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes.
Boebel TA and Hartwig JF.
Journal of the American Chemical Society, 130(24), 7534-7535 (2008)
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