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540293

Tetraalkylammonium carbonate, polymer-bound

macroporous, 40-90 mesh, extent of labeling: 2.5-3.5 mmol/g loading

Synonym(s):

MP-carbonate resin

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About This Item

UNSPSC Code:
12352209
PubChem Substance ID:
24878455
NACRES:
NA.22
MDL number:
MFCD03101751
Form:
macroporous
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form

macroporous

Quality Level

100

reaction suitability

reaction type: solution phase peptide synthesis, reactivity: proton reactive

extent of labeling

2.5-3.5 mmol/g loading

particle size

40-90 mesh

SMILES string

[O-]C([O-])=O.C=Cc1ccccc1.C=Cc2ccc(C=C)cc2.CC[N+](CC)(CC)Cc3ccccc3.CC[N+](CC)(CC)Cc4ccccc4

InChI

1S/2C13H22N.C10H10.C8H8.CH2O3/c2*1-4-14(5-2,6-3)12-13-10-8-7-9-11-13;1-3-9-5-7-10(4-2)8-6-9;1-2-8-6-4-3-5-7-8;2-1(3)4/h2*7-11H,4-6,12H2,1-3H3;3-8H,1-2H2;2-7H,1H2;(H2,2,3,4)/q2*+1;;;/p-2

InChI key

RBIYTBCFDIQNIC-UHFFFAOYSA-L

Application

Polymer-bound tetraalkylammonium carbonate is a polymer-supported base used for scavenging acidic molecules. It can be used in polymer-assisted solution-phase (PASP) Suzuki reactions.

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB3560
MKCZ0015
MKCX7392
MKCT3393
MKCS0324

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Polymer-assisted solution-phase (PASP) Suzuki couplings employing an anthracene-tagged palladium catalyst.
Lan P, et al.
The Journal of Organic Chemistry, 68(25), 9678-9686 (2003)
S R Stauffer et al.
Journal of combinatorial chemistry, 2(4), 318-329 (2000-07-13)
Most ligands for the estrogen receptor (ER) are not well suited for synthesis by combinatorial means, because their construction involves a series of carbon-carbon bond forming reactions that are not uniformly high yielding. In previous work directed to overcoming this
Recent applications of polymer-supported reagents and scavengers in combinatorial, parallel, or multistep synthesis.
Thompson L A.
Current Opinion in Chemical Biology, 4(3), 324-337 (2000)
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Global Trade Item Number

SKUGTIN
540293-5G04061832945835
540293-25G04061832945828