550256
Silver methanesulfonate
solid
Synonym(s):
Silver methylsulfonate, Methanesulfonic acid silver salt
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About This Item
Linear Formula:
AgSO3CH3
CAS Number:
Molecular Weight:
202.97
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
219-199-2
MDL number:
Product Name
Silver methanesulfonate,
form
solid
Quality Level
reaction suitability
core: silver, reagent type: catalyst
mp
252-256 °C (lit.)
SMILES string
[Ag+].CS([O-])(=O)=O
InChI
1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
InChI key
MLKQJVFHEUORBO-UHFFFAOYSA-M
Application
Catalyst for:
- Heterocyclization reactions
- CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,β-unsaturated ketones and esters
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Articles
Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.
Claudio Pettinari et al.
Inorganic chemistry, 50(21), 11173-11183 (2011-10-18)
Five new silver(I) complexes of formulas [Ag(Tpms)] (1), [Ag(Tpms)(PPh(3))] (2), [Ag(Tpms)(PCy(3))] (3), [Ag(PTA)][BF(4)] (4), and [Ag(Tpms)(PTA)] (5) {Tpms = tris(pyrazol-1-yl)methanesulfonate, PPh(3) = triphenylphosphane, PCy(3) = tricyclohexylphosphane, PTA = 1,3,5-triaza-7-phosphaadamantane} have been synthesized and fully characterized by elemental analyses, (1)H, (13)C
Chad E Wujcik et al.
Journal of separation science, 33(6-7), 826-833 (2010-01-21)
Hydrophilic retention coefficients for 17 peptides were calculated based on retention coefficients previously published for TSKgel silica-60 and were compared with the experimental elution profile on a Waters Atlantis HILIC silica column using TFA and methanesulfonic acid (MSA) as ion-pairing
Siddheshwar K Chauthe et al.
Bioorganic & medicinal chemistry letters, 22(6), 2251-2256 (2012-02-22)
A series of dimeric phloroglucinol compounds were synthesized in a single step using commercially available phloroglucinol and methanesulfonic acid. Based on the reported anticancer activity of plant derived dimeric phloroglucinols, these synthesized compounds were evaluated for their in vitro anti-proliferative
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 550256-25G | 04061833548301 |
| 550256-5G | 04061833373422 |