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550787

Vanadyl acetylacetonate

Name: Vanadyl acetylacetonate
Brand: ALDRICH

98%

Synonym(s):

VO(acac)₂, Vanadium(IV)-oxy acetylacetonate

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About This Item

Linear Formula:

OV(C₅H₇O₂)₂

CAS Number:

3153-26-2

Molecular Weight:

265.16

UNSPSC Code:

12352103

NACRES:

NA.23

PubChem Substance ID:

24879146

EC Number:

221-590-8

Beilstein/REAXYS Number:

4138236

MDL number:

MFCD00000032

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Properties

Quality Level

100

assay

98%

mp

235 °C (dec.) (lit.)

SMILES string

CC(=O)\C=C(\C)O[V](=O)O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/q;;;+2/p-2/b2*4-3-;;

InChI key

JFHJZWAQYMGNBE-SUKNRPLKSA-L

Description

Application

Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.

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pictograms

GHS07

signalword

Warning

hcodes

H302,H315,H319,H335

pcodes

P261 - P264 - P271 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

New Mechanism for the Reduction of Vanadyl Acetylacetonate to Vanadium Acetylacetonate for Room Temperature Flow Batteries.

Jack S Shamie et al.

ChemSusChem, 10(3), 533-540 (2016-11-20)

In this study, a new mechanism for the reduction of vanadyl acetylacetonate, VO(acac)

New Oxidovanadium(IV) Coordination Complex Containing 2-Methylnitrilotriacetate Ligands Induces Cell Cycle Arrest and Autophagy in Human Pancreatic Ductal Adenocarcinoma Cell Lines.

Szymon Kowalski et al.

International journal of molecular sciences, 20(2) (2019-01-13)

Pancreatic cancer is characterized by one of the lowest five-year survival rates. In search for new treatments, some studies explored several metal complexes as potential anticancer drugs. Therefore, we investigated three newly synthesized oxidovanadium(IV) complexes with 2-methylnitrilotriacetate (bcma3-), N-(2-carbamoylethyl)iminodiacetate (ceida3-)

Doped and un-doped vanadium dioxide thin films prepared by atmospheric pressure chemical vapour deposition from vanadyl acetylacetonate and tungsten hexachloride: the effects of thickness and crystallographic orientation on thermochromic properties.

Binions R,et al.

Journal of Materials Chemistry, 17, 4652-4660 (2007)

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Global Trade Item Number

SKU	GTIN
550787-50G	04061832576565
550787-10G	04061832576329