556955
2,8,9-Triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane
Synonym(s):
[2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane-2,8,9-tris(1-methylethyl)]
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
PN(CH(CH3)2)CH2CH2NCH2CH2N(CH(CH3)2)(CH2CH2N(CH(CH3)2))
CAS Number:
Molecular Weight:
300.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
refractive index
n20/D 1.4830 (lit.)
Quality Level
density
0.922 g/mL at 25 °C (lit.)
SMILES string
CC(C)N1CCN2CCN(C(C)C)P1N(CC2)C(C)C
InChI
1S/C15H33N4P/c1-13(2)17-10-7-16-8-11-18(14(3)4)20(17)19(12-9-16)15(5)6/h13-15H,7-12H2,1-6H3
InChI key
DFRWCJYSXGNOFD-UHFFFAOYSA-N
Application
Catalyst used in the synthesis of β-hydroxyesters and α,β-unsaturated esters
Base used in an attempt to produce higherly reactive no-carrier-added fluoride for labeling of radiopharmaceuticals and used in the synthesis of monomeric alumatranes
Deprotonation agent used to study the nucleophilic reactivities of benzenesulfonyl-substituted carbanions
Catalyst involved in:
Deprotonation agent used to study the nucleophilic reactivities of benzenesulfonyl-substituted carbanions
Catalyst involved in:
- Synthesis of polymer-supported proazaphosphatranes for catalysis of amidation and transesterification reactions
- Wadsworth-Emmons reactions
- Mukaiyama aldol reactions
- Synthesis of aryl alcohols via addition reactions
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
185.0 °F - closed cup
flash_point_c
85 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Wadhwa, K.; Verkade, J. G.
The Journal of Organic Chemistry, ASAP-ASAP (2009)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 556955-1G | 04061826733059 |
| 556955-5G | 04061833548370 |