559873
Dess-Martin periodinane solution
0.3 M in methylene chloride
Synonym(s):
1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one, Dess-Martin reagent, Triacetoxyperiodinane
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About This Item
CAS Number:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Level
reaction suitability
reagent type: oxidant
concentration
0.3 M in methylene chloride
bp
40 °C
density
1.369 g/mL at 25 °C
functional group
iodo
storage temp.
2-8°C
SMILES string
CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12
InChI
1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChI key
NKLCNNUWBJBICK-UHFFFAOYSA-N
Application
Widely used reagent for the mild oxidation of alcohols to aldehydes and ketones.
signalword
Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
ppe
Eyeshields, Faceshields, Gloves
Regulatory Information
危险化学品
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Dess, D. B.; Martin, J. C.
The Journal of Organic Chemistry, 48, 4155-4155 (1983)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 559873-5ML | 04061832583259 |
| 559873-25ML | 04061838135841 |