561002
2-Bromo-3,3,3-trifluoro-1-propene
97%
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About This Item
Linear Formula:
BrC(CF3)=CH2
CAS Number:
Molecular Weight:
174.95
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Assay:
97%
InChI
1S/C3H2BrF3/c1-2(4)3(5,6)7/h1H2
SMILES string
FC(F)(F)C(Br)=C
InChI key
QKBKGNDTLQFSEU-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.3550 (lit.)
bp
29-30 °C (lit.)
storage temp.
2-8°C
General description
2-Bromo-3,3,3-trifluoro-1-propene can be added to N2 gas in order to enhance its fire suppression efficiency.
Application
2-Bromo-3,3,3-trifluoro-1-propene may be used in the synthesis of 3,3,3 -trifluoropropynyllithium anion via treatment with lithium diisopropylamide at a very low temperature(-78oC).
signalword
Warning
hcodes
Hazard Classifications
Repr. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves
Regulatory Information
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Nucleophilic addition of 3, 3, 3-trifluoropropynyllithium to d-glyceraldimine: Concise synthesis of both enantiomers of 5, 5, 5-trifluoronorvaline
Chen Q, et al.
Journal of Fluorine Chemistry, 128(10), 1182-1186 (2007)
Synthesis of trifluoromethylated and gem-difluoromethylenated biologically interesting compounds from fluorine-containing synthons
Qing L F and Zheng F
Synlett, 2011(08), 1052-1072 (2011)
Fire protection with bromoalkene/nitrogen gaseous mixtures
Zou Y, et al.
Industrial & Engineering Chemistry Research, 40(21), 4649-4653 (2001)
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