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567159

1,1′-Bis(phenylphosphinidene)ferrocene

greener alternative

Greener Alternative

97%, solid

Synonym(s):

1,1′-(Ferrocenediyl)phenylphosphine

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About This Item

Linear Formula:
C5H4PC6H5C5H4Fe
CAS Number:
72954-06-4
Molecular Weight:
292.09
UNSPSC Code:
12352005
PubChem Substance ID:
24880349
NACRES:
NA.22
MDL number:
MFCD04974069
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Product Name

1,1′-Bis(phenylphosphinidene)ferrocene, 97%

Quality Segment

100

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

88-92 °C (lit.)

functional group

phosphine

greener alternative category

Aligned

storage temp.

2-8°C

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3

InChI

1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;

InChI key

HKOUDNXXOXEYNZ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. Ferrocene phosphine ligands are used as catalytic components in asymmetric hydrogenation reactions, enabling efficient and selective synthesis of chiral compounds, offering a greener, potentially more sustainable option for pharmaceutical manufacturing. Click here for more information.

Application

Reactant for:
  • Preparation of macrocyclic tridentate ferrocenylphosphine ligands
  • Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
  • Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
  • Ring-opening reactions via ring slippage
  • Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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