570214
trans-2-Phenylvinylboronic acid pinacol ester
Synonym(s):
(E)-4,4,5,5-Tetramethyl-2-(2-phenylvinyl)-1,3,2-dioxaborolane, (E)-4,4,5,5-Tetramethyl-2-styryl-1,3,2-dioxaborolane, 4,4,5,5-Tetramethyl-2-((E)-2-phenylethenyl)-1,3,2-dioxaborolane, trans-2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)styrene, trans-2-Styreneboronic acid pinacol ester
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About This Item
Linear Formula:
C6H5CH=CHBO2C2(CH3)4
CAS Number:
Molecular Weight:
230.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
mp
27-33 °C (lit.)
Quality Segment
functional group
phenyl
SMILES string
[H]\C(B1OC(C)(C)C(C)(C)O1)=C(\[H])c2ccccc2
InChI
1S/C14H19BO2/c1-13(2)14(3,4)17-15(16-13)11-10-12-8-6-5-7-9-12/h5-11H,1-4H3/b11-10+
InChI key
ARAINKADEARZLZ-ZHACJKMWSA-N
Application
Reactant for:
- Oxidative coupling reactions catalyzed by areneruthenium
- Cycloaddition reactions
- Preparation of allyl vinyl ethers via Cu-catalyzed coupling with alcohols
- Preparation of 5-vinyl-3-pyridinecarbonitriles as PKCθ inhibitors
- Diastereoselective addition to zincated hydrazones and stereospecific trapping of boron/zinc bimetallic intermediates by carbon electrophiles
- Regioselective and stereoselective Pd-catalyzed chelate-controlled intermolecular oxidative Heck reactions
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
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