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577766

Molybdenum hexacarbonyl

Name: Molybdenum hexacarbonyl
Brand: ALDRICH

≥99.9% trace metals basis (excluding W) purified by sublimation

Synonym(s):

Molybdenumhexacarbonyl, Hexacarbonylmolybdenum(0)

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About This Item

Linear Formula:

Mo(CO)₆

CAS Number:

13939-06-5

Molecular Weight:

264.00

NACRES:

NA.23

PubChem Substance ID:

24880893

UNSPSC Code:

12352103

EC Number:

237-713-3

MDL number:

MFCD00003466

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Properties

vapor density

9.1 (vs air)

assay

≥99.9% trace metals basis

form

solid

purified by

sublimation

reaction suitability

core: molybdenum, reagent type: catalyst

bp

156 °C (lit.)

mp

150 °C (dec.) (lit.)

density

1.96 g/mL at 25 °C (lit.)

SMILES string

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChI key

KMKBZNSIJQWHJA-UHFFFAOYSA-N

Description

General description

Atomic number of base material: 42 Molybdenum

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pictograms

GHS06

signalword

Danger

hcodes

H331

pcodes

P261 - P271 - P304 + P340 + P311 - P403 + P233 - P405 - P501

Hazard Classifications

Acute Tox. 3 Inhalation

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Articles

High Purity Metalorganic Precursors for CPV Device Fabrication

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Nanowire Synthesis: From Top-Down to Bottom-Up

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

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Aminocarbonylations employing Mo(CO)6 and a bridged two-vial system: allowing the use of nitro group substituted aryl iodides and aryl bromides.

Patrik Nordeman et al.

The Journal of organic chemistry, 77(24), 11393-11398 (2012-12-05)

A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the

Research spotlight: Microwave chemistry enabling the synthesis of biologically relevant amines.

John Spencer

Future medicinal chemistry, 2(2), 161-168 (2011-03-24)

Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and

Theoretical studies on the Mo-catalyzed asymmetric intramolecular Pauson-Khand-type [2+2+1] cycloadditions of 3-allyloxy-1-propynylphosphonates.

Qingxi Meng et al.

Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)

Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative

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Global Trade Item Number

SKU	GTIN
577766-5G	04061832628943
577766-25G	04061833390061