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Merck
CN

57903

(Iodomethyl)trimethylsilane

≥99.0% (GC)

Synonym(s):

(Trimethylsilyl)methyl iodide

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About This Item

Linear Formula:
(CH3)3SiCH2I
CAS Number:
Molecular Weight:
214.12
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-123-6
Beilstein/REAXYS Number:
1731485
MDL number:
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Quality Level

assay

≥99.0% (GC)

refractive index

n20/D 1.491

bp

139-141 °C (lit.)

density

1.443 g/mL at 25 °C (lit.)

functional group

iodo

SMILES string

C[Si](C)(C)CI

InChI

1S/C4H11ISi/c1-6(2,3)4-5/h4H2,1-3H3

InChI key

VZNYXGQMDSRJAL-UHFFFAOYSA-N

Other Notes

Starting material for the preparation of 2-(trimethylsilyl)ethyl-triphenylphosphonium iodide used for the synthesis of allyl silanes; Used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions


pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

84.2 °F - closed cup

flash_point_c

29 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Articles

Review SET mechanism in photoredox catalysis for sustainable reactions and rearrangement of oxaziridines.


E. Vedejs et al.
The Journal of Organic Chemistry, 48, 4773-4773 (1983)
D. Seyferth et al.
The Journal of Organic Chemistry, 42, 3104-3104 (1977)
I. Fleming et al.
Synthesis, 446-446 (1979)



Global Trade Item Number

SKUGTIN
O022500004061833836750
Y000054304061833795613
Y0000543-0.008MG04061832621432
O-902-1ML04061834212430
O0225000-50MG04061832621401
O5254-50MG04061834233985
57903-5ML04061837912382
57903-25ML04061832629551