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Merck
CN

57903

(Iodomethyl)trimethylsilane

≥99.0% (GC)

Synonym(s):

(Trimethylsilyl)methyl iodide

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About This Item

Linear Formula:
(CH3)3SiCH2I
CAS Number:
Molecular Weight:
214.12
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-123-6
Beilstein/REAXYS Number:
1731485
MDL number:
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Product Name

(Iodomethyl)trimethylsilane, ≥99.0% (GC)

InChI key

VZNYXGQMDSRJAL-UHFFFAOYSA-N

InChI

1S/C4H11ISi/c1-6(2,3)4-5/h4H2,1-3H3

SMILES string

C[Si](C)(C)CI

assay

≥99.0% (GC)

refractive index

n20/D 1.491 (lit.)
n20/D 1.491

bp

139-141 °C (lit.)

density

1.443 g/mL at 25 °C (lit.)

functional group

iodo

Quality Level

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Other Notes

Starting material for the preparation of 2-(trimethylsilyl)ethyl-triphenylphosphonium iodide used for the synthesis of allyl silanes; Used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

84.2 °F - closed cup

flash_point_c

29 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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E. Vedejs et al.
The Journal of Organic Chemistry, 48, 4773-4773 (1983)
E. Vedejs et al.
The Journal of Organic Chemistry, 50, 2170-2170 (1985)
I. Fleming et al.
Synthesis, 446-446 (1979)
D. Seyferth et al.
The Journal of Organic Chemistry, 42, 3104-3104 (1977)
Aleksandra Sadowska et al.
Frontiers in pharmacology, 11, 952-952 (2020-07-28)
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