Skip to Content
Merck
CN

Key Documents

View All Documentation

590444

Methyl (4-chlorobenzoyl)acetate

Synonym(s):

(p-Chlorobenzoyl)acetic acid methyl ester, Methyl 3-(4-chlorophenyl)-3-oxopropionate

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C10H9ClO3
CAS Number:
22027-53-8
Molecular Weight:
212.63
NACRES:
NA.22
PubChem Substance ID:
24881280
UNSPSC Code:
12352100
MDL number:
MFCD00216520
Form:
solid
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

form

solid

mp

42-46 °C (lit.)

SMILES string

COC(=O)CC(=O)c1ccc(Cl)cc1

InChI

1S/C10H9ClO3/c1-14-10(13)6-9(12)7-2-4-8(11)5-3-7/h2-5H,6H2,1H3

InChI key

OIPOJEDRCKVDJK-UHFFFAOYSA-N

Application

Reactant involved in:
  • Oxidative coupling with aminopyridines
  • Enantioselective hydrogenation of unprotected β-enamine esters
  • Intramolecular cyclization
  • Oxidative alkylation of benzylic C-H bonds
  • Tandem oxidative coupling and annulation of phenols

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library