590592
Hafnium(IV) chloride
purified by sublimation, 99.9% trace metals basis
Synonym(s):
Hafnium tetrachloride, Tetrachlorohafnium
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About This Item
Linear Formula:
HfCl4
CAS Number:
Molecular Weight:
320.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
236-826-5
MDL number:
Assay:
99.9% trace metals basis
Form:
powder
vapor pressure
1 mmHg ( 190 °C)
assay
99.9% trace metals basis
form
powder
purified by
sublimation
reaction suitability
core: hafnium
impurities
≤1500.0 ppm Trace Metal Analysis
SMILES string
Cl[Hf](Cl)(Cl)Cl
InChI
1S/4ClH.Hf/h4*1H;/q;;;;+4/p-4
InChI key
PDPJQWYGJJBYLF-UHFFFAOYSA-J
Application
Hafnium(IV) chloride can be used as a catalyst:
- To synthesize α-aminophosphonates via the one-pot three-component reaction of aldehyde, amine, and phosphite.
- For the conversion of carbohydrates into 5-hydroxymethylfurfural in ionic liquids.
- For parallel synthesis of 1,2-disubstituted benzimidazoles from N-substituted phenylenediamines and aldehydes.
- A precursor to prepare hafnium oxide nanoparticles via sol-gel method.
- A starting material to synthesize bulky guanidinato hafnium(iv) chloridecomplexes.
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
supp_hazards
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Hafnium oxide nanoparticles synthesized via sol-gel route for an efficient detection of volatile organic compounds at room temperature
Anamitra Chattopadhyay and Jhasaketan Nayak
Materials Science in Semiconductor Processing, 139 , 106336-106336 (2022)
Synthesis and crystal structures of bulky guanidinato zirconium (IV) and hafnium (IV) chloride complexes
Cameron Jones, et al.
Journal of Chemical Crystallography, 42, 866-870 (2012)
Highly efficient synthesis of ?-aminophosphonates catalyzed by hafnium(IV) chloride
Xiao-Chuan Li, et al.
Tetrahedron Letters, 57, 1782-1785 (2016)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 590592-25G | 04061833599402 |
| 590592-5G | 04061832639505 |