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593192

Cu-TMEDA catalyst

Name: Cu-TMEDA catalyst
Brand: ALDRICH

Synonym(s):

Di-μ-hydroxo-bis[(N,N,N′.N′-tetramethylethylenediamine)copper(II)] chloride

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About This Item

Empirical Formula (Hill Notation):

C₁₂H₃₄Cl₂Cu₂N₄O₂

CAS Number:

30698-64-7

Molecular Weight:

464.42

NACRES:

NA.22

PubChem Substance ID:

24881335

UNSPSC Code:

12161600

MDL number:

MFCD01321163

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Properties

Quality Level

100

reaction suitability

core: copper, reagent type: catalyst

mp

131-132 °C (lit.)

SMILES string

[H]O[Cu]Cl.[H]O[Cu]Cl.CN(C)CCN(C)C.CN(C)CCN(C)C

InChI

1S/2C6H16N2.2ClH.2Cu.2H2O/c2*1-7(2)5-6-8(3)4;;;;;;/h2*5-6H2,1-4H3;2*1H;;;2*1H2/q;;;;2*+2;;/p-4

InChI key

XSGFQMSXIWLPOB-UHFFFAOYSA-J

Description

Application

Catalyst for:

Asymmetric conjugate addition reactions
1,3-dipolar cycloaddition of pyrazolidinone-based dipoles to terminal alkynes (precatalyst)
Oxidative N-arylation of imidazoles
Oxidative coupling copolymerization
Tandem phosphorous-carbon bond formation-oxyfunctionalization reactions
Benzylation and allylation of amides

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Global Trade Item Number

SKU	GTIN
593192-5G	04061833356616