593192
Cu-TMEDA catalyst
Synonym(s):
Di-μ-hydroxo-bis[(N,N,N′.N′-tetramethylethylenediamine)copper(II)] chloride
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About This Item
Empirical Formula (Hill Notation):
C12H34Cl2Cu2N4O2
CAS Number:
Molecular Weight:
464.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/2C6H16N2.2ClH.2Cu.2H2O/c2*1-7(2)5-6-8(3)4;;;;;;/h2*5-6H2,1-4H3;2*1H;;;2*1H2/q;;;;2*+2;;/p-4
SMILES string
[H]O[Cu]Cl.[H]O[Cu]Cl.CN(C)CCN(C)C.CN(C)CCN(C)C
InChI key
XSGFQMSXIWLPOB-UHFFFAOYSA-J
reaction suitability
core: copper, reagent type: catalyst
mp
131-132 °C (lit.)
Quality Level
Related Categories
Application
Catalyst for:
- Asymmetric conjugate addition reactions
- 1,3-dipolar cycloaddition of pyrazolidinone-based dipoles to terminal alkynes (precatalyst)
- Oxidative N-arylation of imidazoles
- Oxidative coupling copolymerization
- Tandem phosphorous-carbon bond formation-oxyfunctionalization reactions
- Benzylation and allylation of amides
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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