593230
Phenyllithium solution
1.9 M in dibutyl ether
Synonym(s):
PhLi
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About This Item
Empirical Formula (Hill Notation):
C6H5Li
CAS Number:
Molecular Weight:
84.04
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506502
Quality Segment
concentration
1.9 M in dibutyl ether
density
0.835 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]c1ccccc1
InChI
1S/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;
InChI key
NHKJPPKXDNZFBJ-UHFFFAOYSA-N
Application
Phenyllithium solution can be used to synthesize:
- 1-Acetyl-1′-diphenylphosphinoferrocene from ferrocenophane.
- Ethyl 2-acetylimino-1-benzyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from ethyl 1-benzyl-6-bromo-2-imino-1,2-dihydroquinoline-3-carboxylate.
- Ethyl 2-amino-1-benzoyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from (E)-ethyl 2-(acetylimino)-1-benzoyl-6-bromo-1,2-dihydroquinoline-3-carboxylate.
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signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
77.0 °F - closed cup
flash_point_c
25 °C - closed cup
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