595675
2-Bromo-5-fluoropyridine
97%
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About This Item
Empirical Formula (Hill Notation):
C5H3BrFN
CAS Number:
Molecular Weight:
175.99
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
97%
bp
80-83 °C/44 mmHg (lit.)
mp
30-31 °C (lit.)
functional group
bromo
fluoro
SMILES string
Fc1ccc(Br)nc1
InChI
1S/C5H3BrFN/c6-5-2-1-4(7)3-8-5/h1-3H
InChI key
UODINHBLNPPDPD-UHFFFAOYSA-N
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Application
2-Bromo-5-fluoropyridine can be used in the synthesis of the following:
- 5-fluoro-2-phenylpyridine via Suzuki coupling reaction with phenylboronic acid
- 5-fluoro-2-(p-tolyl)pyridine via Suzuki coupling reaction with p-tolylboronic acid
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
163.4 °F - closed cup
Flash Point(C)
73 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Find documentation for the products that you have recently purchased in the Document Library.
"A fast and oxygen-promoted protocol for the ligand-free Suzuki reaction of 2-halogenated pyridines in aqueous media"
Liu C and Yang W
Chemical Communications (Cambridge, England), 41, 6267-6269 (2009)
Lee K and Lee HP
Tetrahedron Letters, 49(27), 4302-4305 (2008)
"A General and Highly Efficient Method for the Construction of Aryl-Substituted N-Heteroarenes"
Liu C, et al.
European Journal of Organic Chemistry, 1010(29), 5548-5551 (2010)
Tetrahedron Letters, 48, 1191-1191 (2007)
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