630918
2-Bromo-N-methylaniline
95%
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About This Item
Linear Formula:
BrC6H4NHCH3
CAS Number:
Molecular Weight:
186.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Product Name
2-Bromo-N-methylaniline, 95%
InChI
1S/C7H8BrN/c1-9-7-5-3-2-4-6(7)8/h2-5,9H,1H3
SMILES string
CNc1ccccc1Br
InChI key
SMVIAQFTVWDWDS-UHFFFAOYSA-N
assay
95%
refractive index
n20/D 1.6070 (lit.)
bp
107-109 °C/12 mmHg (lit.)
density
1.589 g/mL at 25 °C (lit.)
functional group
amine
bromo
Quality Level
Related Categories
Application
2-Bromo-N-methylaniline can be used to synthesize benzimidazole derivatives, via one pot N-arylation of amides/cyclic amides in the presence of copper iodide nanoparticles. It can also be used in the synthesis of alkyltelluro-substituted aromatic amines, which can show radical trapping ability.
General description
2-Bromo-N-methylaniline can be synthesized via the reduction of 2-bromoformylanilide.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
217.4 °F - closed cup
flash_point_c
103 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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"Syntheses of 2-Unsubstituted 1H-1, 3-Benzazaphospholes from N-Formyl-2-bromoanilides"
Ghalib M, et al.
Heteroatom Chem., 4(78), 452-459 (2013)
Poon F-J, et al.
Chemistry?A European Journal , 22(36), 12891-12903 (2016)
"Nanoparticle mediated organic synthesis (NAMO-synthesis): CuI-NP catalyzed ligand free amidation of aryl halides"
Kumar A and Bishnoi KA
Royal Society of Chemistry Advances, 4(78), 41631- 41635 (2014)
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