631655
2,2′-Bis(methoxymethoxy)-1,1′-binaphthalene
97%
Synonym(s):
2,2′-Bis(methoxymethoxy)-1,1′-binaphthyl
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About This Item
Linear Formula:
(CH3OCH2OC10H6)2
CAS Number:
Molecular Weight:
374.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/C24H22O4/c1-25-15-27-21-13-11-17-7-3-5-9-19(17)23(21)24-20-10-6-4-8-18(20)12-14-22(24)28-16-26-2/h3-14H,15-16H2,1-2H3
SMILES string
COCOc1ccc2ccccc2c1-c3c(OCOC)ccc4ccccc34
InChI key
YIAQRNNJNMLGTP-UHFFFAOYSA-N
assay
97%
reaction suitability
reagent type: ligand
mp
92-96 °C (lit.)
General description
2,2′-Bis(methoxymethoxy)-1,1′-binaphthalene is an aryl alkyl ether that can undergo nickel catalyzed cross-coupling reaction with aryl Grignard reagent to form the aryl-aryl cross-coupling product.
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Cross-Coupling of Aryl/Alkenyl Ethers with Aryl Grignard Reagents through Nickel-Catalyzed C? O Activation.
Xie LG and Wang ZX.
Chemistry?A European Journal , 17(18), 4972-4975 (2011)
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