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Merck
CN

646075

p-Tolylmagnesium bromide solution

0.5 M in diethyl ether

Synonym(s):

4-Methylphenylmagnesium bromide

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About This Item

Linear Formula:
CH3C6H4MgBr
CAS Number:
4294-57-9
Molecular Weight:
195.34
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24883432
MDL number:
MFCD00000040
Beilstein/REAXYS Number:
636491

Key Documents

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InChI key

ZRJNGFJIBZKXTP-UHFFFAOYSA-M

SMILES string

Cc1ccc([Mg]Br)cc1

InChI

1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in diethyl ether

Quality Level

100

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Related Categories

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-40.0 °F - closed cup - Solvent

flash_point_c

-40 °C - closed cup - Solvent

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
0000244677
0000219243
0000244677
0000219243
0000209737

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Derek E Williams et al.
Journal of the American Chemical Society, 140(24), 7611-7622 (2018-05-29)
Stimuli-responsive materials are vital for addressing emerging demands in the advanced technology sector as well as current industrial challenges. Here, we report for the first time that coordinative integration of photoresponsive building blocks possessing photochromic spiropyran and diarylethene moieties within
Ekaterina A Dolgopolova et al.
Journal of the American Chemical Society, 141(13), 5350-5358 (2019-03-07)
Electronic structure modulation of metal-organic frameworks (MOFs) through the connection of linker "wires" as a function of an external stimulus is reported for the first time. The established correlation between MOF electronic properties and photoisomerization kinetics as well as changes

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