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650412

Borane tetrahydrofuran complex solution

1.0 M in THF, contains 0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

Synonym(s):

Borane-THF (1:1), Borane-THF complex (1:1)

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About This Item

Linear Formula:
BH3OC4H8
CAS Number:
14044-65-6
Molecular Weight:
85.94
PubChem Substance ID:
24883750
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
3668402
MDL number:
MFCD00012429
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contains

0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

Quality Level

200

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.880 g/mL at 25 °C

functional group

ether

storage temp.

2-8°C

SMILES string

B.C1CCOC1

InChI

1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3

InChI key

RMCYTHFAWCWRFA-UHFFFAOYSA-N

Application

Used to reduce nylon surface amide groups to secondary amines.
New, Safer, NIMBA-Stabilized BH3 THF Solutions
This useful reagent for reductions and other transformations is now safer in transport utilizing this new stabilizer

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
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Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3 - Water-react. 1

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBT2215
SHBS1652
SHBQ2172
SHBM2076
SHBH7962

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Hisanori Ueki et al.
The Journal of organic chemistry, 71(9), 3506-3511 (2006-04-22)
This paper presents a highly stereoselective synthesis of trifluoro- or difluoromethylated olefins via an S(N)2' type fluorination or reductions of gem-difluorinated vinyloxiranes. Their fluorination with HF-Py furnished trifluoromethylated allylic alcohols with exclusive E selectivity. On the other hand, their reduction
Polymer, 47, 4916-4916 (2006)
Jung Seok Lee et al.
Macromolecular bioscience, 15(9), 1314-1322 (2015-06-04)
We designed poly(β-amino esters) (PBAEs) bearing both UV light- and pH-sensitive groups and used PBAEs to prepare nanoparticles (NPs) that can be utilized for on-demand burst release of guest molecules in response to multiple triggers. Due to the presence of

Global Trade Item Number

SKUGTIN
650412-100ML04061838136091
650412-4X25ML04061838136114
650412-800ML04061838136121
650412-18L-C04061838232540