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Merck
CN

653667

Pd(0) EnCat® 30NP

wet, nanoparticles, extent of labeling: 0.4 mmol/g Pd(0) loading (dry basis)

Synonym(s):

Palladium(0), microencapsulated in polyurea matrix

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About This Item

Empirical Formula (Hill Notation):
Pd
Molecular Weight:
106.42
UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
MFCD06798789

Key Documents

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form

wet, nanoparticles

contains

0.35-0.43 mmol/g pallladium(0) (dry basis), 45% water

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

extent of labeling

0.4 mmol/g Pd(0) loading (dry basis)

weight

Unit weight includes weight of water.

Quality Level

100

Related Categories

General description

Pd(0) EnCat® 30NP may be used as a catalyst for the selective reduction of aromatic aldehydes, ketones and epoxides to form the corresponding alcohols via hydrogenation.

Other Notes

Encapsulated Pd catalyst reduction of aryl ketones and benzyl ethers.
Matrix content 30%

Legal Information

Pd EnCat® technology.
EnCat is a registered trademark of Reaxa Ltd.

pictograms

Flame
GHS02

signalword

Danger

hcodes

H251

Hazard Classifications

Self-heat. 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
00428TH
11821CE
07716HD
07616HD
06907CD

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Steven V Ley et al.
Organic letters, 5(24), 4665-4668 (2003-11-25)
[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.

Related Content

Pd EnCat™ Encapsulated Palladium Catalysts

Homogeneous palladium catalysts are widely utilized due to their versatility, reactivity and functional group tolerance.

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