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Merck
CN

653667

Pd(0) EnCat® 30NP

wet, nanoparticles, extent of labeling: 0.4 mmol/g Pd(0) loading (dry basis)

Synonym(s):

Palladium(0), microencapsulated in polyurea matrix

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About This Item

Empirical Formula (Hill Notation):
Pd
Molecular Weight:
106.42
UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
MFCD06798789

Key Documents

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Product Name

Pd(0) EnCat® 30NP, wet, nanoparticles, extent of labeling: 0.4 mmol/g Pd(0) loading (dry basis)

form

wet
nanoparticles

contains

0.35-0.43 mmol/g pallladium(0) (dry basis)
45% water

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

extent of labeling

0.4 mmol/g Pd(0) loading (dry basis)

weight

Unit weight includes weight of water.

Quality Level

100

Related Categories

General description

Pd(0) EnCat® 30NP may be used as a catalyst for the selective reduction of aromatic aldehydes, ketones and epoxides to form the corresponding alcohols via hydrogenation.

Legal Information

Pd EnCat® technology.
EnCat is a registered trademark of Reaxa Ltd.

Other Notes

Encapsulated Pd catalyst reduction of aryl ketones and benzyl ethers.
Matrix content 30%

pictograms

Flame
GHS02

signalword

Danger

hcodes

H251

Hazard Classifications

Self-heat. 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
00428TH
11821CE
07716HD
07616HD
06907CD

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Steven V Ley et al.
Organic letters, 5(24), 4665-4668 (2003-11-25)
[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.

Related Content

Pd EnCat™ Encapsulated Palladium Catalysts

Homogeneous palladium catalysts are widely utilized due to their versatility, reactivity and functional group tolerance.

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