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Merck
CN

656577

1,3-Diisopropylimidazolium chloride

greener alternative

97%, solid

Synonym(s):

N,N′-(Isopropyl)imidazolium chloride

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About This Item

Empirical Formula (Hill Notation):
C9H17ClN2
CAS Number:
139143-09-2
Molecular Weight:
188.70
UNSPSC Code:
12352005
PubChem Substance ID:
24884209
NACRES:
NA.22
MDL number:
MFCD03840577

Key Documents

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Product Name

1,3-Diisopropylimidazolium chloride, 97%

SMILES string

[Cl-].CC(C)n1cc[n+](c1)C(C)C

InChI

1S/C9H17N2.ClH/c1-8(2)10-5-6-11(7-10)9(3)4;/h5-9H,1-4H3;1H/q+1;/p-1

InChI key

DOFXKPAOJLLPII-UHFFFAOYSA-M

assay

97%

form

solid

reaction suitability

reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

182-186 °C

greener alternative category

Aligned,

Quality Level

200

Related Categories

Application

1,3-Diisopropylimidazolium chloride may be used to prepare:
  • 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.
  • (C9H7)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).
  • Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.
Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN6513
BCCL7220
BCCH8706
BCCH5932
BCCG7625

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A dinuclear Bi (III) complex of a 1, 3-disubstituted imidazole-2-thione and its use as a transmetallation agent toward Pd (II).
Jagenbrein M, et al.
Journal of Organometallic Chemistry, 796, 11-16 (2015)
Amide Synthesis from Alcohols and Amines Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes.
Dam JH, et al.
Chemistry?A European Journal , 16(23), 6820-6827 (2010)
Indenylnickel (II) N-heterocyclic carbene complexes: Synthesis via indene elimination and catalytic activity for ethylene dimerization.
Sun HM, et al.
Organometallics, 24(2), 331-334 (2005)
Chen C and Hong SH.
Organic & Biomolecular Chemistry, 9(1), 20-26 (2011)

Protocols

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