656577
1,3-二异丙基咪唑氯
97%, solid
别名:
N,N′-(异丙基)氯化咪唑鎓
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关于此项目
经验公式（希尔记法）:
C9H17ClN2
化学文摘社编号:
分子量:
188.70
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
1,3-二异丙基咪唑氯, 97%
SMILES string
[Cl-].CC(C)n1cc[n+](c1)C(C)C
InChI
1S/C9H17N2.ClH/c1-8(2)10-5-6-11(7-10)9(3)4;/h5-9H,1-4H3;1H/q+1;/p-1
InChI key
DOFXKPAOJLLPII-UHFFFAOYSA-M
assay
97%
form
solid
reaction suitability
reagent type: catalyst
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
182-186 °C
greener alternative category
Quality Level
Application
1,3-Diisopropylimidazolium chloride may be used to prepare:
- 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.
- (C9H7)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).
- Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.
Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.
Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen
Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
A dinuclear Bi (III) complex of a 1, 3-disubstituted imidazole-2-thione and its use as a transmetallation agent toward Pd (II).
Jagenbrein M, et al.
Journal of Organometallic Chemistry, 796, 11-16 (2015)
Amide Synthesis from Alcohols and Amines Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes.
Dam JH, et al.
Chemistry?A European Journal , 16(23), 6820-6827 (2010)
Indenylnickel (II) N-heterocyclic carbene complexes: Synthesis via indene elimination and catalytic activity for ethylene dimerization.
Sun HM, et al.
Organometallics, 24(2), 331-334 (2005)
Chen C and Hong SH.
Organic & Biomolecular Chemistry, 9(1), 20-26 (2011)
实验方案
Acetylene chemistry's versatile applications from organic synthesis to bioorganic chemistry demand efficient synthesis methods.
乙炔化学一直是并且仍然是分子科学的重要组成部分。它的潜力和广泛的应用从有机合成到材料科学再到生物有机化学。一些例子是烯二炔（DNA切割剂），“点击化学”工具和构建块。 因此，它引发了对高效合成炔烃的需求。
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