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About This Item
Empirical Formula (Hill Notation):
C8H16Cl2Rh2
CAS Number:
Molecular Weight:
388.93
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Product Name
Di-μ-chlorotetraethylene dirhodium(I),
form
solid
Quality Level
reaction suitability
core: rhodium
reagent type: catalyst
storage temp.
−20°C
SMILES string
Cl[Rh].Cl[Rh].C=C.C=C.C=C.C=C
InChI
1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/q;;;;;;2*+1/p-2
InChI key
OOQJCPOXJFCGCR-UHFFFAOYSA-L
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Application
Di-μ-chlorotetraethylene dirhodium(I) may be used in the preparation of Π-bound rhodium organometallic complexes of ROMP-derived poly(1,5-cyclooctadiene) (poly(COD)). [ROMP= Ring-Opening Metathesis Polymerization; COD= 1,5-cyclooctadiene]
Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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