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659932

Buchwald Ligands Kit I

Name: Buchwald Ligands Kit I
Brand: ALDRICH

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About This Item

NACRES:

NA.22

UNSPSC Code:

12350000

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Properties

Quality Level

100

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

functional group

phosphine

Description

General description

These ligands have varying steric and electronic properties and are useful for rapid screening of catalysis conditions. It is in sampler format with individual components packaged for multiple experiments and mini scale-up.

Learn more about Buchwald Phosphine Ligands

Application

Catalysis Screening Kits

A kit containing 6 phosphine ligands used by the Buchwald Group in palladium-catalyzed aryl C- and N- coupling reactions.

Legal Information

Usage subject to US Patents 6307087 and 6395916.

Kit Components Also Available Separately

Product No.

Description

SDS & Pricing

638021
DavePhos, 97% 1 g
SDS

638064
XPhos, 98% 1 g
SDS

638072
SPhos, 98% 1 g
SDS

638080
tBuXPhos, 98% 1 g
SDS

638099
CyJohnPhos, 97% 1 g
SDS

638439
JohnPhos, 97% 1 g
SDS

hcodes

H413

pcodes

P273 - P501

Hazard Classifications

Aquatic Chronic 4

Storage Class

10 - Combustible liquids

wgk

WGK 3

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Articles

Buchwald Phosphine Ligands

Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

Buchwald Phosphine Ligands

Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

Expanding Pd-catalyzed C-N bond-forming processes: the first amidation of aryl sulfonates, aqueous amination, and complementarity with Cu-catalyzed reactions.

Xiaohua Huang et al.

Journal of the American Chemical Society, 125(22), 6653-6655 (2003-05-29)

The first general method for the Pd-catalyzed amination of aryl tosylates and benzenesulfonates was developed utilizing ligand 1, which belongs to a new generation of biaryl monophosphine ligands. In addition, the new catalyst system for the first time enables amidation

A rationally designed universal catalyst for Suzuki-Miyaura coupling processes.

Shawn D Walker et al.

Angewandte Chemie (International ed. in English), 43(14), 1871-1876 (2004-04-01)

Global Trade Item Number

SKU	GTIN
659932-1KT	04061833549056