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661058

Methoxy(cyclooctadiene)rhodium(I) dimer

solid

Synonym(s):

[Rh(OMe)(1,5-cod)]2

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About This Item

Empirical Formula (Hill Notation):
C18H30O2Rh2
CAS Number:
12148-72-0
Molecular Weight:
484.24
UNSPSC Code:
12161600
PubChem Substance ID:
24884497
NACRES:
NA.22
MDL number:
MFCD08457639
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Product Name

Methoxy(cyclooctadiene)rhodium(I) dimer,

form

solid

Quality Segment

100

reaction suitability

core: rhodium, reagent type: catalyst

mp

192-225 °C

storage temp.

−20°C

SMILES string

CO[Rh].CO[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.2CH3O.2Rh/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*-1;2*+1/b2*2-1-,8-7-;;;;

InChI key

BDQMDBOKWREKIT-MIXQCLKLSA-N

Application

Efficient and Selective Catalysts for Asymmetric Synthesis
Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation
Rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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