661058
Methoxy(cyclooctadiene)rhodium(I) dimer
solid
Synonym(s):
[Rh(OMe)(1,5-cod)]2
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About This Item
Empirical Formula (Hill Notation):
C18H30O2Rh2
CAS Number:
Molecular Weight:
484.24
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Methoxy(cyclooctadiene)rhodium(I) dimer,
form
solid
Quality Segment
reaction suitability
core: rhodium, reagent type: catalyst
mp
192-225 °C
storage temp.
−20°C
SMILES string
CO[Rh].CO[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
InChI
1S/2C8H12.2CH3O.2Rh/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*-1;2*+1/b2*2-1-,8-7-;;;;
InChI key
BDQMDBOKWREKIT-MIXQCLKLSA-N
Application
Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation
Rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
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