Key Documents

View All Documentation

661902

(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid

Name: (<I>S</I>)-(+)-2-(<I>tert</I>-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid
Brand: ALDRICH

96%

Synonym(s):

(S)-(+)-2-(tert-Butyl)-3-methyl-4-oxoimidazolidinium trifluoroacetate, (S)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid salt

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₇N₂O₃F₃

CAS Number:

900503-70-0

Molecular Weight:

270.25

NACRES:

NA.22

PubChem Substance ID:

24884554

UNSPSC Code:

12352005

MDL number:

MFCD08443793

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

Quality Level

100

assay

96%

form

solid

mp

99-103 °C

functional group

carboxylic acid, fluoro

SMILES string

OC(=O)C(F)(F)F.CN1[C@H](NCC1=O)C(C)(C)C

InChI

1S/C8H16N2O.C2HF3O2/c1-8(2,3)7-9-5-6(11)10(7)4;3-2(4,5)1(6)7/h7,9H,5H2,1-4H3;(H,6,7)/t7-;/m0./s1

InChI key

HKHKOEMMPVPVOS-FJXQXJEOSA-N

Description

General description

(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid is a Macmillan imidazolidinone organocatalyst, which is generally employed in asymmetric transformation reactions.

Application

Highly selective organocatalyst for 1,3-dipolar addition and Friedel-Crafts alkylation.

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

pictograms

GHS07

signalword

Warning

hcodes

H302,H319

pcodes

P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P337 + P313

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Macmillan Imidazolidinone Organocatalysts

Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

Highly enantioselective transfer hydrogenation of alpha, beta-unsaturated ketones

Martin NJA and List B

Journal of the American Chemical Society, 128(41), 13368-13369 (2006)

Jen, W. S. et al

Journal of the American Chemical Society, 122, 9874-9874 (2000)

New strategies in organic catalysis: the first enantioselective organocatalytic Friedel-Crafts alkylation.

N A Paras et al.

Journal of the American Chemical Society, 123(18), 4370-4371 (2001-07-18)

View All Related Papers

Global Trade Item Number

SKU	GTIN
661902-500MG	04061833473887