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About This Item
Empirical Formula (Hill Notation):
C2H4Cl3NO3S
CAS Number:
Molecular Weight:
228.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Related Categories
Application
Nitrogen source in an intermolecular rhodium-catalyzed (662623) amination of C-H bonds.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
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Kristin Williams Fiori et al.
Journal of the American Chemical Society, 129(3), 562-568 (2007-01-18)
Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiomeric 3 degrees centers, displays high
Articles
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
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