665029
1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium chloride
solid
Synonym(s):
1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride
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About This Item
Product Name
1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium chloride,
form
solid
Quality Segment
reaction suitability
reagent type: ligand
reaction type: Ring-Opening Polymerization
mp
263-280 °C
SMILES string
[Cl-].Cc1cc(C)c(N2CC[N+](=C2)C34CC5CC(CC(C5)C3)C4)c(C)c1
InChI
1S/C22H31N2.ClH/c1-15-6-16(2)21(17(3)7-15)23-4-5-24(14-23)22-11-18-8-19(12-22)10-20(9-18)13-22;/h6-7,14,18-20H,4-5,8-13H2,1-3H3;1H/q+1;/p-1/t18-,19+,20-,22-;
InChI key
MJOMRTQWLPXDJQ-ZFCGJYDVSA-M
Application
- Preparation of chelated ruthenium alkoxybenzylidene imidazolidene carbene pivalate catalysts for Z-selective olefin metathesis
- Use in ring-opening metathesis polymerization and ring-closing metathesis reactions via Grubbs catalyst mediated reactions
- Preparation of adamantyl-substituted N-heterocyclic carbene ligands in second-generation Grubbs-type iridium metathesis catalysis
Legal Information
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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